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Recovering old batteries
Conditioners that do a three cycle charge / discharge run are ok for recovering
relatively new batteries that may have been mistreated ...radios
left on, or
trickled continuously for weeks. I don't find them very good for recovering
really old batts.
It is useful to know what happens when they discharge
so I usually data log
a 1 amp discharge from "fully charged". I then usually
see a 1.2 volt
voltage step that indicates that one cell has low capacity.
This can
sometimes be cured by the "conditioner".
More often
with the very old batteries i find that one cell (or more) is "stuck" at zero
volts. So fully charged shows about 1.3volts low (the approx
voltage of a
fully charged NiCad.) The conditioner will not normally "unstick" these. I
use a current limited power supply (a Kingshill actually)
and apply a change
of around 3 amps (for AA cell packs up to 1200mAhr) for a
period of about 10
seconds...no longer and then allow a resting
period of 20
seconds for the
temperature to dissipate. This needs to be done until the
battery terminal
voltage rises to the right value and does not
drop too
rapidly when the
charging voltage is removed. I do not recommend you do this
as it is possible
if the pressure inside the battery increases
to have the
cell explode with
some violence (but I am still alive and I'm a coward !).
Once the battery
seems to hold the right terminal voltage put it one a
normal charger,
preferably at the C/20 rate and overcharge by 100% i.e. 28
hours .instead of
14 hrs. Once the battery has been recovered to reasonable
terminal voltage
then cycling it with rapid charge / discharge, will get it
back to some sort
of usable capacity with luck. It doesn't work on every
battery but it is well
worth trying. You may find that a battery recovered
like this will work when
taken from the charger but may not hold charge as
well as a new battery. This
is probably due to whiskers across the plates,
some rough treatment will
improve things sometimes. Modelers seem to be
able to use batts like this
and they charge the cells in a few minutes (in
a
poly bag in a bucket of
water !! ) and also flatten them as quickly.
The ideal way to recover
cells is individually rather than in series across
the the series string, but
this is not always possible. I have re-celled
laptop
batteries by just
replacing the faulty (stuck) ones, it is not
recommended as the capacity
should be balanced but it is a cheap experiment
and it often
works when it is
not economic to pay £100 for a replacement for
an old machine.
Thanks to Alan G3 NYK
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